Ultrafiltration is a membrane separation technology
whose membrane has a porous asymmetric structure. The ultrafiltration
filtration process is a solution separation process driven by the pressure
difference on both sides of the membrane and based on the principle of
mechanical sieving. The operating pressure is usually 0.01~0.3 MPa, the sieving
pore size is from 0.002~0.1μm, and the molecular weight cutoff is Around
1000~100,000 daltons.
★ The separation process does not undergo phase change and consumes less energy;
★ The separation process can be carried out at normal temperature, which is suitable for the concentration or purification of some heat-sensitive substances such as juices, biological preparations and certain pharmaceuticals;
★ The separation process only uses low pressure as the driving force. The equipment and process flow are simple and easy to operate, manage and maintain;
★ It has a wide range of applications. Ultrafiltration separation technology can be used for any solute molecular weight between 1000 and 500,000 Daltons or solute size between 0.005 and 0.1μm. In addition, by using a series of membranes with different molecular weight cutoffs, each component in a mixture of solutes with different molecular weights can be classified by molecular weight.
Ultrafiltration can operate in three operating modes:
full flow or dead-end filtration, cross-flow filtration and concentrated water
discharge filtration (Concentrate Bleed).
The cleaning process of ultrafiltration includes air
scrubbing, water backwashing and forward washing of physical cleaning process,
as well as chemical enhanced backwash and chemical cleaning (Cleaning In Place)
of chemical cleaning process. Among them, air scrubbing uses compressed air to
form strong turbulence in the water to loosen the particle pollutants trapped
on the membrane surface, while water backwashing uses the direction of the
water flow opposite to the direction of water production. The water flow passes
through the membrane pores, which can remove the deep layers of the membrane
pores and The positive wash removes pollutants on the membrane surface and removes
the remaining pollutants from the backwash, and discharges the gas in the
membrane module. Chemically enhanced backwashing and chemical cleaning use
chemicals to remove contamination formed on the surface and interior of the
ultrafiltration membrane such as colloids, organic matter, and inorganic salts.
Increased cleaning frequency and cleaning intensity will help to remove various
pollutants more thoroughly.
There are many materials that can be used to make
ultrafiltration membranes, including polyvinylidene fluoride (PVDF),
polyethersulfone (PES), polypropylene (PP), polyethylene (PE), polysulfone
(PS), polyacrylonitrile (PAN) ), polyvinyl chloride (PVC), etc. In the early
1990s, polyethersulfone materials were commercially used; and in the late
1990s, polyvinylidene fluoride ultrafiltration membranes with better
performance began to be widely used in the water treatment industry.
Polyvinylidene fluoride and polyethersulfone have become the most widely used
ultrafiltration membrane materials. When ultrafiltration is used for water
treatment, the chemical stability and hydrophilicity of its materials are the
two most important properties. Chemical stability determines the service life
of membrane materials under the action of acids, alkalis, oxidants,
microorganisms, etc., and is also directly related to the choice of cleaning
processes; hydrophilicity determines the anti-pollution ability of membrane
materials against pollutants in water, affecting the membrane of flux.